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کاربرد نوع شرط:
- جایگاه : پژوهشی
- مجله: Quarterly Journal of Applied Chemical Research
- نوع مقاله: Journal Article
- کلمات کلیدی: polyvinyl alcohol,Drug delivery systems,ATRP,N-vinylpyrrolidone
- چکیده:
- چکیده انگلیسی: In current study,a hydrogel based on biocompatible polymerwas prepared. The functionalization of polyvinyl alcohol (PVA)with epichlorohydrin(ECH) to produce epichlorohydrin-g-polyvinyl alcohol (PVA/ECH) as a suitable macroinitiator for atom transfer radical polymerization (ATRP) reaction was investigated.ThenN-vinyl pyrrolidone (NVP) waspolymerized on the surface of macroinitiatorin presence of CuCl as a catalyst and Pentamethyldiethylenetriamine (PMDETA) as aligand using ATRP to produce PNVP-g-PVA. The synthesized copolymer was characterized by Fourier transform infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC). Also equilibrium swelling was studied in distilled water and indicated the sustained expansion of them. At last, loading capacity and release profiles of ceftriaxone as a model drug from the hydrogel were determined by UV– Vis absorption measurement at λmax= 243 nm. In vitro drug release behavior was investigated in three different media (HCl solution: pH=3 and bicarbonate buffer solutions: pH=7 and pH=8).
- انتشار مقاله: 11-10-1395
- نویسندگان: Sedigheh Ehsanimehr,Peyman Najafi Moghadam,Nasim Movagharnezhad,Amir Reza Fareghi
- مشاهده
- جایگاه : پژوهشی
- مجله: Asian Journal of Green Chemistry
- نوع مقاله: Journal Article
- کلمات کلیدی: Dye removal,Congo red,MWCNT,Melamine,Schiff-base
- چکیده:
- چکیده انگلیسی: Carbon nanotubes (CNTs) have been extensively explored for adsorption applications due to their well-defined cylindrical hollow structure, large surface area, high aspect ratios, hydrophobic wall, and easily modified surfaces. In the present work, a poly Schiff-base was synthesized with capability to remove the dye pollutant from aqueous solutions. For this propose, firstly, multi-walled carbon nanotube (MWCNT) was modified with melamine, then the melamine-modified MWCNT was further reacted with 3-pyridinecarboxaldehyde to synthesize the final poly Schiff-base. The prepared adsorbent was employed to assess the removal of the dye pollutants from aqueous solutions and Congo red (CR) was selected as typical dye. Different adsorption parameters such as pH, adsorbent amount, initial concentration of the dye, and contact time were investigated and optimized. By adjusting these parameters, the adsorption percentage reached to the value of 92%. Moreover, the adsorption isotherms were studied and fitted with the Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) models. The kinetic studies were carried out by using the Lagergren pseudo-first-order and the Ho pseudo-second-order equations. The adsorbent was also characterized by FT-IR, TGA, and SEM techniques.
- انتشار مقاله: 09-05-1398
- نویسندگان: Somayeh Farajzadeh,Peyman Najafi Moghadam,Jabbar Khalafy
- مشاهده