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کاربرد نوع شرط:
- جایگاه : پژوهشی
- مجله: Journal of Water and Environmental Nanotechnology
- نوع مقاله: Journal Article
- کلمات کلیدی: Isotherm,kinetic,Nano-adsorbent,Polyaniline,Amido Black 10B
- چکیده:
- چکیده انگلیسی: In the present study, adsorptive properties of Polyaniline (PAn) were investigated for Amido Black 10B dye in aqueous solution. Different variables, including adsorption time, adsorbent dosage, solution pH and initial dye concentration were changed, and their effects on dye adsorption onto PAn nano-adsorbent were investigated. The study yielded the result that an increase in pH decreases the adsorption efficiency of nano-adsorbent. Also, Dye adsorption capacity increased with increase in the initial dye concentration. Optimum adsorption time and nano-adsorbent dosage were obtained 30 min and 0.1 gr, respectively. Kinetic studies illustrated that the Amido Black 10B dye adsorption process onto PAn nano-adsorbent followed the pseudo-second-order model, which indicates that the adsorption process is chemisorption-controlled. Also, adsorption equilibrium data were fitted to Freundlich isotherm. The maximum dye adsorption capacity, predicted by the Langmuir isotherm, was 142.85 mg/g. Moreover, Dubinin-Radushkevich isotherm showed that the adsorption of dye onto PAn nano-adsorbent is a chemisorption process.
- انتشار مقاله: 06-06-1395
- نویسندگان: Marjan Tanzifi,Mohsen Mansouri,Maryam Heidarzadeh,Kobra Gheibi
- مشاهده
- جایگاه : پژوهشی
- مجله: Journal of Renewable Energy and Environment
- نوع مقاله: Journal Article
- کلمات کلیدی: Nanofluid,Thermal conductivity,Solar Collector,Thermal Performance,Vacuum Tube
- چکیده:
- چکیده انگلیسی: The enhancement of the thermal performance of Vacuum Tube Solar Collectors (VTSC) was studied by using alumina nanofluid as working fluid. VTSC is a simple and commonly utilized type of collector. This study established the heat transfer experimental model of all glass VTSCs used in a forced-circulation solar water heating system using alumina nanofluid as base fluid. Al2O3 (with an average particle size of 15 nm) nanoparticles were provided and utilized to prepare nanofluids at a low mass concentration (0.5–1 wt.%). The thermal performances of VTSC were 15.3%, 25.7%, and 27.2% for the deionized water and Al2O3/water nanofluids with 0.5 and 1.0 wt. % as the working fluid, respectively. Generally, for Al2O3/water nanofluids with mass concentrations of 0.5 and 1.0 wt. %, the thermal performance increased by 67.9% and 77.7%, respectively, superior to that of vacuum tube using deionized water as the working fluid. Experimental results also showed that, for all three experimental tests, the thermal efficiency of the VTSC would increase by enhancing the average solar radiation.
- انتشار مقاله: 13-12-1397
- نویسندگان: Seyed Amir Hossein Zamzamian,Mohsen Mansouri
- مشاهده
- جایگاه : پژوهشی
- مجله: Journal of Chemical Health Risks
- نوع مقاله: Journal Article
- کلمات کلیدی: Photocatalytic degradation,MTBE,TiO2 – ZnO - CuO nanoparticles,Response surface modeling
- چکیده:
- چکیده انگلیسی: In this study, the TiO2-ZnO-CuO nanoparticles were primed by sol-gel method characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM), for degradation of MTBE solution in water. The effectiveness of the treatment method applied for the degradation of MTBE based on an advanced photocatalytic oxidation process was investigated. The three various key parameters were optimized using response surface modeling namely: pH, TiO2-ZnO-CuO concentration and the initial MTBE concentrations. The optimized values were obtained at the PH (7), TiO2-ZnO-CuO concentration (1.49 g/L), and the initial MTBE concentration (31.46 mg/L). Finally, kinetics reaction of degradtion MTBE was carried in the optimum conditions.
- انتشار مقاله: 12-10-1395
- نویسندگان: Mohsen Mansouri,Mohsen Nademi,Mohammad Ebrahim Olya,Hossein Lotfi
- مشاهده
- جایگاه : پژوهشی
- مجله: Iranian Journal of Chemistry and Chemical Engineering
- نوع مقاله: Journal Article
- کلمات کلیدی: Nano-structure catalyst,Co–Mn spinel oxide,Fischer–Tropsch Synthesis
- چکیده:
- چکیده انگلیسی: Nano-structure of Co–Mn spinel oxide was prepared by thermal decomposition method using [Co(NH3)4CO3]MnO4 as the precursor. The properties of the synthesized material were characterized by X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Transmission Electron Microscopy (TEM), surface area measurements, Energy-Dispersive X-ray (EDX) spectroscopy analysis, UV-Vis spectrophotometer (UV-Vis), Fourier Transform InfraRed (FT-IR), Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) analyses. The results show that Co–Mn spinel oxide is spherical in shape and possess crystallite size is about 12 nm. The catalytic activity and product selectivity were also investigated, in a micro-reactor (Fischer–Tropsch Synthesis (FTS) reaction) and the results compared with conventional Co-Mn oxide catalyst. The catalyst performance increased as the particle size of the catalyst decreased. Moreover, the olefin to paraffin ratios was increased, compared to the conventional catalyst.
- انتشار مقاله: 12-10-1395
- نویسندگان: Ghobad Mansouri,Mohsen Mansouri
- مشاهده
- جایگاه : پژوهشی
- مجله: Advances in Environmental Technology
- نوع مقاله: Journal Article
- کلمات کلیدی: Chlorella vulgaris,CO2, Photobioreactor,Predictive modeling
- چکیده:
- چکیده انگلیسی: The objective of this study was to investigate the growth rate of Chlorella vulgaris for CO2 biofixation and biomass production. Six mathematical growth models (Logistic, Gompertz, modified Gompertz, Baranyi, Morgan and Richards) were used to evaluate the biomass productivity in continuous processes and to predict the following parameters of cell growth: lag phase duration (λ), maximum specific growth rate (μmax), and maximum cell concentration (Xmax). The low root-mean-square error (RMSE) and high regression coefficients (R2) indicated that the models employed were well fitted to the experiment data and it could be regarded as enough to describe biomass production. Using statistical and physiological significance criteria, the Baranyi model was considered the most appropriate for quantifying biomass growth. The biological variables of this model are as follows: μmax=0.0309 h−1, λ=100 h, and Xmax=1.82 g/L.
- انتشار مقاله: 07-02-1395
- نویسندگان: Mohsen Mansouri,Mohsen Mansouri,Mohsen Mansouri
- مشاهده
- جایگاه : پژوهشی
- مجله: Advances in Environmental Technology
- نوع مقاله: Journal Article
- کلمات کلیدی: Photocatalytic degradation,Response surface method,MTBE,TiO2-ZnO-CoO nanoparticles
- چکیده:
- چکیده انگلیسی: Since groundwaters are a major source of drinking water, their pollution with organic contaminants such as methyl tertiary-butyl ether (MTBE) is a very significant issue. Hence, this research investigated the photocatalytic degradation of MTBE in an aqueous solution of TiO2-ZnO-CoO nanoparticle under UV irradiation. In order to optimize photocatalytic degradation, response surface methodology was applied to assess the effects of experimental variables such as catalyst loading, initial concentration of MTBE and pH on the dye removal efficiency. The optimal condition to achieve the best degradation for the initial concentration of 30.58 mg/L of MTBE was found at a pH of 7.68 and a catalyst concentration of 1.68 g/L after 60 min.
- انتشار مقاله: 24-04-1395
- نویسندگان: Hossein Lotfi,Mohsen Nademi,Mohsen Mansouri,Mohammad Ebrahim Olya
- مشاهده