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کاربرد نوع شرط:
- جایگاه : پژوهشی
- مجله: Journal of Ultrafine Grained and Nanostructured Materials
- نوع مقاله: Journal Article
- کلمات کلیدی: thiosemicarbazone,CuO nanoparticles,Copper(I) Iodide
- چکیده:
- چکیده انگلیسی: In this paper, we have focused on the preparation and characterization of copper oxide nanoparticles by solid state thermal decomposition of copper(I) iodide in the presence of thiosemicarbazone ligands without the need for a catalyst, employing toxic solvent, template or surfactant and complicated equipment, which makes it efficient, one-step, simple and environment-friendly. CuO nanoparticles were achieved at 600 ˚C for 3 h as black products and characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD) and transmission electron microscopy (TEM). The FT-IR spectra of black powders prepared show absorption maxima at ≈ 525 cm-1 which are due to Cu-O stretching mode. Also, all the X-ray diffraction peaks could be readily assigned to those of crystalline CuO. The absence of any residual ligand traces or other phases in the FT-IR spectra and XRD patterns confirmed the preparation of high purity and single phase copper oxide nanoparticles. The TEM images show that the synthesized copper oxide nanoparticles are of plate like shape with average diameters of 10 – 20 nm. On the basis of the above results, the use of thiosemicarbazone ligands at the presence of suitable transition metal ions is potentially capable of forming other transition metal oxide nanoparticles by solid state thermal decomposition.
- انتشار مقاله: 03-03-1394
- نویسندگان: Ensieh Shahsavani,Nourollah Feizi,Aliakbar Dehno Khalaji
- مشاهده
- جایگاه : پژوهشی
- مجله: Chemical Methodologies
- نوع مقاله: Journal Article
- کلمات کلیدی: Zinc(II),Mononuclear,Distorted tetrahedral
- چکیده:
- چکیده انگلیسی: In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and four-coordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.
- انتشار مقاله: 25-07-1397
- نویسندگان: Aliakbar Dehno Khalaji,Ensieh Shahsavani,Michal Dusek,Monika Kucerakova,Wolfgang Hornfeck
- مشاهده