چکیده انگلیسی:
The NMR spectra of azo dyes, 5-arylazobarbituric (5a-g), 5-arylazo-1,3-dimethylbarbituric (6a-g) and 5-arylazothiobarbituric acids (7a-g) were studied in DMSO-d6 in different concentrations. An intramolecular hydrogen bond was observed and indicating that the hydrazone forms is mostly predominant. The peak of the hydrazone proton was severely broadened and its chemical shift appeared at down field due to intramolecular hydrogen bond. Existence of nitro group at ortho-position on phenyl ring caused the chemical shift value of the proton of hydrazone form in 5a-7a to be more deshielded than other hydrazone protons in 5bg− 7b-g due to bifurcated intramolecular hydrogen bond and anisotropic ring-current effect. Dyes 6 shows two tautomers in NMR time scale at low concentration in DMSO-d6.
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