چکیده انگلیسی:
A series of x(Co, Mn)/TiO2 catalysts (x=2–12wt.%) containing 25%Co and 75%Mn were prepared by the co-impregnation method. All prepared catalysts have been tested in Fischer-Tropsch synthesis for production of C2-C4 olefins. It was found that the catalyst containing 8wt.%(Co,Mn)/TiO2 is an optimal catalyst for production of C2-C4 olefins. The effect of operation conditions such as the H2/CO molar feed ratios, temperature,Gas Hourly Space Velocity (GHSV)and total reaction pressure on the catalytic performance of optimal catalyst was investigated. Characterizations of both precursors and catalysts were carried out using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Brunauer-Emmett-Teller (BET) specific surface area measurement, Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC).
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